The court will now review in the months ahead whether to permanently invalidate the French government's ban - unless in the meantime Daimler withdraws its claim.
The dispute could tarnish the image of the new refrigerant R1234yf, made by Honeywell International Inc and DuPont , and makes it more likely that automakers will need to search for a new chemical that meets an EU directive on air-conditioning refrigerants.
Daimler, which says 60 percent of its sales in France are affected by the ban, argued before the tribunal on Friday that R1234yf poses a potential fire hazard.
France says its ban is legal under European Union rules designed to protect the environment and public health. It points out that Germany's KBA motoring authority itself has found that R1234yf poses no serious danger.
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